Jones Oxidation for Primary and Secondary Alcohols

Standards
1-Butanol, 2-Butanol, t-Butyl alcohol

Procedure
Dissolve 10 mg or 2 drops of the unknown in 1 mL of pure acetone in a test tube and add to the solution 1 small drop of Jones reagent (chronic acid in sulfuric acid). A positive test is marked by the formation of a green color within 15 seconds upon addition of the orange-yellow reagent to a primary or secondary alcohol. Aldehydes also give a positive test, but tertiary alcohols do not.
The Jones reagent will already be prepared for you.

Positive Test
A positive test for aldehydes and primary or secondary alcohols consists in the production of an opaque suspension with a green to blue color. Tertiary alcohols give no visible reaction within 2 seconds, the solution remaining orange in color. Disregard any changes after 15 seconds.

Complications

Enols may give a positive test.
Phenols give a dark colored solution which is not blue-green like a positive test.
Cleaning up
Place all solutions in the appropriate waste container